By N. Purdie, Harry G. Brittain

ISBN-10: 0444895086

ISBN-13: 9780444895080

Positive aspects specific points of round dichroism and examines the way it might be of counsel to staff within the box. The textual content discusses the actual phenomena linked to dissymmetric compounds which offer upward thrust to the round dichroism influence, and stories the instrumentation on hand.

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Extra info for Analytical Applications of Circular Dichroism

Example text

Warner and co-workers [28] have developed a multidimensional FDCD spectrometer using an intensified diode array as the light detection device. Their system combines the optical arrangement depicted in Fig. 6 for the FDCD experiment, with the polychromatorlmultichannel light detection arrangement illustrated in Fig. 4. However, instead of using polarization modulation in combination with synchronous amplification, a non-alternating (dc) detection strategy was employed. This was necessitated by the time limitations imposed by the readout rate of the diode array.

From ref. [ 151. For a given CCD array, one dimension, (such as the vertical plane), could be used to define distinct wavelength regions. Intensity information for a given wavelength interval for the two, oppositely polarized states would then be alternately stored in the exposed and unexposed regions defined by the CCD mask. After readout of the two planes in the CCD array, the CD information could be obtained from the integrated exposure information in the two image planes as accomplished conventionally.

However, as was discussed earlier, PEMs are driven at a resonant frequency which usually varies between 50 and 100 kHz, and this exceeds the readout rate of the photodiode array by three orders-of-magnitude. Charge coupled devices (CCD) and charge injection devices (CID) are solid state sensors which are fabricated as true two dimensional arrays, as opposed to the onedimensional arrangement characteristic of the diode array. In addition to these differing spatial characteristics, CCDs and CIDs are more sensitive than conventional diode arrays and are read out by a different mechanism.

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Analytical Applications of Circular Dichroism by N. Purdie, Harry G. Brittain

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